SECTION 1 - COMPOSITION AND INGREDIENT INFORMATION

COMPONENT/CAS #

% BY
WEIGHT

EXPOSURE LIMITS

CANCER
DESIGNATION

Newsprint (Cellulose Fiber)
#65996-61-4

Not less than
80%

PEL-TWA=15mg/m3  total dust (PNOC)
PEL-TWA=15mg/m3  respirable fraction
TLV-TWA=10mg/m3  inhalable, no asbestos and quartz<1% (PNOC)
TLV-TWA=3mg/m3  respirable, no asbestos
and quartz<1% (PNOC)

None

Boric Acid H3 BO3
#10043-35-3

Not more than
12%

Same

None

Borax Pentahydrate Na2 B4O7,
5H2O #12179-04-3

Not less than
9%

Same

None

Boric acid is classified as hazardous under the OSHA Hazard Communication Standard based on animal chronic toxicity studies.  Refer to Sections 3 and 11 for details on hazards.  This product is not considered hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200.

HMIS Rating

 

National Fire Protection Association (NFPA)

 

Health

1

Red (Flammability)

0

Flammability

1

Yellow (Reactivity)

0

Reactivity

0

Blue (Acute Health)

1*

Personal Protection

E

*ChronicEffects

 

SECTION 2 - HAZARD IDENTIFICATION

EMERGENCY OVERVIEW
Avoid extreme heat and open flame.  May emit carbon monoxide gas and boric acid and other hazardous particulates during thermal decomposition.  CelluBOR Insulation is a finely divided, light gray material with no perceptible odor.  It presents no unusual hazard if involved in a fire.

Physical Characteristics

 

Boiling Point (F)

Not applicable

Vapor Pressure (mm Hg)

Not applicable

Vapor Density

Not applicable

Solubility in Water

Insoluble; dispersible

Specific Gravity (H20=1)

Not applicable

Reactivity in Water

None

Melting Point

Not applicable

Potential Health Effects

 

Inhalation

Slightly irritating to upper respiratory system.  Persons with respiratory problems
should avoid breathing dust.

Eyes

Slight irritant.  In case of eye contact, flush with water.

SECTION 3 -FIRST AID

Eyes

For dust exposure, immediately flush eyes with plenty of water for at least 15 minutes.  Seek medical
attention if irritation persists.

Skin

If skin is exposed, wash with soap and large amounts of water.  If irritation persists, seek medical
attention.

Inhalation

If irritation or difficulty in breathing occurs, remove to fresh air.  Seek medical attention if condition
persists.

Ingestion

Symptoms may include diarrhea, nausea and vomiting.  Seek medical attention if material was ingested
and symptoms occur.

Note to
Physicians

Exposure to dust may aggravate symptoms of persons with pre-existing respiratory tract conditions and
may cause skin and gastrointestinal symptoms.

SECTION 4 - FIRE FIGHTING MEASURES

Flash Point
(Method Used)

Not applicable

Combustible

Material may decompose on contact with extreme temperatures and open flames.

Flammable
Limits

LEL:  Not applicable   UEL:  Not applicable

Autoignition
Temperature

Not determined

Explosion
Hazard

None expected for product based on particle size.  

Extinguishing
Media

Water, dry chemical and other agents rated for a wood fire (Type A fire).  Use Type A rated
extinguisher.

Fire Fighting
Instructions

Evacuate the area and notify the fire department.  If possible, isolate the fire by moving other
combustible materials.  If the fire is small, use a hose-line or extinguisher rated for a Type A fire.  If possible, dike and collect water used to fight fires.  Fire-fighters should wear normal protective equipment (full bunker gear) and positive-pressure, self-contained breathing apparatus.

SECTION 5 - ACCIDENTAL RELEASE MEASURES

Contains water-soluable inorganic mineral salts which may damage trees or vegetation exposed to large quantities.
Land:  shovel, sweep or vacuum product.  Place in disposal container.  Avoid bodies of water.
Water:  large quantities may cause localized contamination of surrounding waters depending on the quantity spilled.  At
high concentrations may damage localized vegetation, fish and other aquatic life.   This product is a non-hazardous waste when spilled or disposed of as defined in the Resource Conservation and Recovery Act (RCRA) regulations (40 CFR
261).  Refer to regulatory information in Section 15 for additional information regarding EPA and California regulations.

SECTION 6 - HANDLING AND STORAGE

General

No special handling is required.  Storage of sealed bags in a dry, indoor location is
recommended.  To maintain product integrity, handle on a “first-in -first-out” basis.  Use good housekeeping and engineering cont rols so that dust levels are below the exposure limits listed
in Section 2.

Storage Temperature

Ambient

Storage Pressure

Atmospheric

Special Sensitivity

None

SECTION 7 - EXPOSURE CONTROLS AND PERSONAL PROTECTION

General Exposure Controls

No specific controls are needed.  Use standard good housekeeping practices and
engineering controls to minimize nuisance levels.

Respiratory Protection

If housekeeping and engineering controls do not maintain nuisance levels below
regulatory limits or dust concentration is unknown, use a NIOSH-Approved Air
Purifying Respirator.

Eye Protection

Wear ANSI-approved eye protection if environment is excessively dusty.

Hand Protection

If skin is broken or sensitive, use gloves

Other Protective Clothing

None

Ventilation

Normal and adequate ventilation

Work/Hygienic Practices

Standard hygienic practices

Occupational Exposure
Limits

Thisproductislisted/regulatedbyOSHA,Cal/OSHAandACGIHas“Particulates
NotOtherwiseClassifiedor“NuisanceDust.”

SECTION 8 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Gray, odorless fiber

Boiling/Melting Point

Not applicable

Bulk Density

9 lb/ft3  compressed

Flash Point

Not applicable

Vapor Pressure

Negligible @ 20 ° C

pH

<8.2 (2.0% suspension @ 25°  C

Solubility in Water

Product is not soluble

Viscosity

Not applicable

SECTION 9 - STABILITY AND REACTIVITY

Stability:  CelluBOR Insulation is a stable product.
Hazardous Decomposition Products:   None
Hazardous Polymerization:  Will not occur
Conditions and Materials to Avoid:  Reaction with strong reducing agents such as metal hydrides or alkali metals will generate hydrogen gas which could create an explosi ve hazard.  Keep away from strong oxidizers, such as concentrated nitric acid, hydrogen peroxide and chlorine.

SECTION 10 - TOXICOLOGICAL INFORMATION

BORIC ACID

Eye

None listed, is expected to be an eye irritant

Skin

Mild irritation based on Standard Draize Test. LDLo, skin, human, 1200 mg/kg

Ingestion

LDLo, oral, human, 429 mg/kg.  LD40, oral, rat, 2600 mg/kg

Inhalation

LCLo, inhalation, rat, 28 mg/m3/4H

Subchronic

TDLo, oral, rat, 45 gm/kg/90D-C

Chronic

TDLo, oral, rat, 244 gm/kg/2Y -C

Teratology

None reported

Reproduction

TDLo, oral, rat, 6600 mg/kg, specific developmental abnormalities - musculoskeletal system

Mutagenicity      Mutation in microorganisms, Escherichia Coli, 17000 ppm/24H.

BORAX PENTAHYDRATE

Eye

Mild eye irritant in rabbits. Fifty years of occupational exposure to borax pentahydrate indicate no adverse effects on human eye. Borax pentahydrate is a constituent of eye lotions.

Skin

Non-irritant. Low acute dermal toxicity; LD50 in rabbits is greater than 2,000 mg/kg of body weight. Borax pentahydrate  is poorly absorbed through intact skin.

Ingestion

Low acute oral toxicity; LD50 in rats is 3,200 to 3,500 mg/kg of body weight

Inhalation

Low acute inhalation toxicity; LC50 in rats is greater than 2.0 mg/l (or g/m3).

Subchronic

None reported

Chronic

None reported

Teratology

None reported

Reproduction

None reported

Mutagenicity

None reported

 

SECTION 11 - ECOLOGICAL INFORMATION

 

BORIC ACID

Ecotoxicity

LC50, Daphnia magna, 133 mg/l/48H.  RfD, oral, human, 0.09 mg/kg/day, testicular
atrophy, spermatogenic arrest.  LC50, Trout, 100 ppm

Chemical Fate
Information

Boron is absorbed into clay particles, with the maximum absorption in the pH range of 7-
9.  The amount of boron absorbed depends on the surface area of the clay.

BORAX PENTAHYDRATE

Ecotoxicity

Boron occurs naturally in sea water at an average concentration of 5 mg B/l and fresh water at 1 mg B/l or less. In dilute aqueous solutions the predominant boron species present is undissociated boric acid.

Chemical Fate
Information

Not listed.

SECTION 12 - DISPOSAL CONSIDERATIONS

Dispose as a non -hazardous waste.

SECTION 13 - TRANSPORT INFORMATION

May be shipped normally as a non -hazardous material.

INTERNATIONAL REGULATIONS

       Land
- Rail/road (RID/ADR)                           : NOT REGULATÝONS.

- Sea (IMO/IMDG)                                 : NOT REGULATIONS.

- Air (ICAO-IATA)                                  : NOT REGULATIONS.

OTHER REGULATIONS                          : NOT AVAIABLE.

NOT RESTRICTED UNDER IATA REGULATION

SECTION 14 - REGULATORY INFORMATION

Superfund:     This   product   is   not   listed   under   the   Comprehensive   Environmental   Response
Compensation and Liability Act (CERCLA) or its 1986 amendments, the Superfund Amendments and Reauthorization Act

(SARA),  including  substances  listed  under  Section  313  of  SARA,  Toxic  Chemicals,  42  USC  11023,  40  CFR  372.65; Section  302  of  SARA  Extremely  Haz ardous  Substances,  42  USC  11002,  40  CFR  355;  or  the  CERCLA  Hazardous Substances list, 42 USC 9604, 40 CFR 302.

RCRA:  This product is not listed as a hazardous waste under any sections of the Resource Conservation and Recovery
Act or regulations (40 CFR 261 et seq.).

Safe Drinking Water Act:  This product is not regulated under the SDWA, 42 USC 300g-1, 40 CFR 141 et seq.   Consult state and

local regulations for possible water quality advisories regarding boron and ammonia.

California Proposition 65:   This product is not listed on any Proposition 65 lists of carcinogens or reproductive toxicants.

OSHA Carcinogen: Not listed.

Clean Water Act (Federal Water Pollution Control Act):   33 USC 1251 et seq.: This product is not itself a discharge
covered by any  water quality criteria of Section 304 of the CWA, 33 USC 1314.   This product is not on the Section 307
List  of  Priority  Pollutants,  33  USC  1317,  40  CFR  116. This  product  is  not  on  the  Section  311  List  of  Hazardous

            Substances, 33 USC 1321, 40 CFR 116.

TSCA No.:  This product does not appear on the EPA TSCA inventory list.  Ammonium sulfate and boric acid appear on the EPA TSCA inventory list under the CAS Nos. 7783-20-2 and 10043-35-3 respectively.

OSHA/Cal/OSHA:   This MSDS document meets the requirements of both OSHA and Cal/OSHA hazard communication standards.  Refer to Section 8 for regulatory exposure limits.

IARC:   The International Agency for Research on Cancer (of the World Health Organization) does not list or categorize this product as a carcinogen.

NTP Annual Report on Carcinogens:   Not listed.

SECTION 15 - OTHER INFORMATION

INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED DEPENDABLE AND
IS ACCURATE AND RELIABLE TO THE BEST OF OUR KNOWLEDGE AND BELIEF, BUT IS NOT GUARANTEED TO
BE SO.   NOTHING HEREIN  IS  TO  BE  CONSTRUED  AS  RECOMMENDING  ANY PRACTICE OR ANY PRODUCT IN VIOLATION OF ANY PATENT OR IN VIOLATION OF ANY LAW OR REGULATION.   THE USER IS RESPONSIBLE TO
DETERMINE THE SUITABILITY OF ANY MATERIAL FOR A SPECIFIC PURPOSE AND ADOPT NECESSARY SAFETY PRECAUTIONS.   WE  MAKE  NO  WARRANTY  AS  TO  RESULTS  TO  BE  OBTAINED  IN  USING  ANY  MATERIAL  AND, SINCE  CONDITIONS  OR  USE  ARE  NOT  UNDER  OUR  CONTROL,  WE  MUST  NECESSARILY  DISCLAIM  ALL LIABILITY WITH RESPECT TO USE OF ANY MATERIAL SUPPLIED BY US.

ABBREVIATIONS

CAS

Chemical Abstract Services (identifies specific
chemical)

OSHA

Occupational Safety and Health Administration

mg/m3

Grams per cubic meter

PNOC

Particulates Not Otherwise Classified

LCLo

Lethal concentration low

PEL

OSHA Permissible Exposure Limit

LDLo

Lethal dose low

ppm

Parts per million

LC50

Lethal concentration 50%

RfD

Reference Dose

LD50

Lethal dose 50%

RTECS

Registry of Toxic Effects of Chemical Substances

LOAEL

Lowest Observed Adverse Effect Level

TDLo

Toxic dose low

Mg/l/H

Milligrams per liter per hour

TLV

ACGIH Threshold Limit Value

Mg/kg

Milligrams per kilogram

TWA

8 hour Time Weighted Average exposure

Mg/ m3

Milligrams per cubic meter

 

 

                                                                  
BIBLIOGRAPHY

1.   The Guide to Occupational Exposure Values, American Conference of Governmental Industrial Hy gienists, 1997.
2.   Registry  of  Toxic  Effects  of  Chemical  Substances,  National  Institute  of  Occupational  Safety  and  Health,  Q-1,
1998.
3.   Dangerous Properties of Industrial Materials, Sax’s, 1997 CD -Folio.
4.   Hazardous Substances Data Bank, Canadian Centre for Occupational Health and Safety, Q-1, 1998.
5.   Integrated Risk Information System, EPA, on-line.
6.   Toxicological Profiles, Agency for Toxic Substances and Disease Registry, U.S. Public Health Service, 1997.
7.   TLVs  and  other  Occupational  Exposure  Values,  American  Conference  of  Governmental  Industrial  Hygienists,
1996.

 

 

 

 

 

© 2008 Eksonser Metal Oxide Cons. Metallurgy Ind. Products and Foreign Trade Ltd.