SECTION 1 - COMPOSITION AND INGREDIENT INFORMATION
COMPONENT/CAS # |
% BY
WEIGHT |
EXPOSURE LIMITS |
CANCER
DESIGNATION |
Newsprint (Cellulose Fiber)
#65996-61-4 |
Not less than
80% |
PEL-TWA=15mg/m3 total dust (PNOC)
PEL-TWA=15mg/m3 respirable fraction
TLV-TWA=10mg/m3 inhalable, no asbestos and quartz<1% (PNOC)
TLV-TWA=3mg/m3 respirable, no asbestos
and quartz<1% (PNOC) |
None |
Boric Acid H3 BO3
#10043-35-3 |
Not more than
12% |
Same |
None |
Borax Pentahydrate Na2 B4O7,
5H2O #12179-04-3 |
Not less than
9% |
Same |
None |
Boric acid is classified as hazardous under the OSHA Hazard Communication Standard based on animal chronic toxicity studies. Refer to Sections 3 and 11 for details on hazards. This product is not considered hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200.
HMIS Rating |
|
National Fire Protection Association (NFPA) |
|
Health |
1 |
Red (Flammability) |
0 |
Flammability |
1 |
Yellow (Reactivity) |
0 |
Reactivity |
0 |
Blue (Acute Health) |
1* |
Personal Protection |
E |
*ChronicEffects |
|
SECTION 2 - HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Avoid extreme heat and open flame. May emit carbon monoxide gas and boric acid and other hazardous particulates during thermal decomposition. CelluBOR Insulation is a finely divided, light gray material with no perceptible odor. It presents no unusual hazard if involved in a fire.
Physical Characteristics |
|
Boiling Point (F) |
Not applicable |
Vapor Pressure (mm Hg) |
Not applicable |
Vapor Density |
Not applicable |
Solubility in Water |
Insoluble; dispersible |
Specific Gravity (H20=1) |
Not applicable |
Reactivity in Water |
None |
Melting Point |
Not applicable |
Potential Health Effects |
|
Inhalation |
Slightly irritating to upper respiratory system. Persons with respiratory problems
should avoid breathing dust. |
Eyes |
Slight irritant. In case of eye contact, flush with water. |
SECTION 3 -FIRST AID
Eyes |
For dust exposure, immediately flush eyes with plenty of water for at least 15 minutes. Seek medical
attention if irritation persists. |
Skin |
If skin is exposed, wash with soap and large amounts of water. If irritation persists, seek medical
attention. |
Inhalation |
If irritation or difficulty in breathing occurs, remove to fresh air. Seek medical attention if condition
persists. |
Ingestion |
Symptoms may include diarrhea, nausea and vomiting. Seek medical attention if material was ingested
and symptoms occur. |
Note to
Physicians |
Exposure to dust may aggravate symptoms of persons with pre-existing respiratory tract conditions and
may cause skin and gastrointestinal symptoms. |
SECTION 4 - FIRE FIGHTING MEASURES
Flash Point
(Method Used) |
Not applicable |
Combustible |
Material may decompose on contact with extreme temperatures and open flames. |
Flammable
Limits |
LEL: Not applicable UEL: Not applicable |
Autoignition
Temperature |
Not determined |
Explosion
Hazard |
None expected for product based on particle size. |
Extinguishing
Media |
Water, dry chemical and other agents rated for a wood fire (Type A fire). Use Type A rated
extinguisher. |
Fire Fighting
Instructions |
Evacuate the area and notify the fire department. If possible, isolate the fire by moving other
combustible materials. If the fire is small, use a hose-line or extinguisher rated for a Type A fire. If possible, dike and collect water used to fight fires. Fire-fighters should wear normal protective equipment (full bunker gear) and positive-pressure, self-contained breathing apparatus. |
SECTION 5 - ACCIDENTAL RELEASE MEASURES
Contains water-soluable inorganic mineral salts which may damage trees or vegetation exposed to large quantities.
Land: shovel, sweep or vacuum product. Place in disposal container. Avoid bodies of water.
Water: large quantities may cause localized contamination of surrounding waters depending on the quantity spilled. At
high concentrations may damage localized vegetation, fish and other aquatic life. This product is a non-hazardous waste when spilled or disposed of as defined in the Resource Conservation and Recovery Act (RCRA) regulations (40 CFR
261). Refer to regulatory information in Section 15 for additional information regarding EPA and California regulations.
SECTION 6 - HANDLING AND STORAGE
General |
No special handling is required. Storage of sealed bags in a dry, indoor location is
recommended. To maintain product integrity, handle on a “first-in -first-out” basis. Use good housekeeping and engineering cont rols so that dust levels are below the exposure limits listed
in Section 2. |
Storage Temperature |
Ambient |
Storage Pressure |
Atmospheric |
Special Sensitivity |
None |
SECTION 7 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
General Exposure Controls |
No specific controls are needed. Use standard good housekeeping practices and
engineering controls to minimize nuisance levels. |
Respiratory Protection |
If housekeeping and engineering controls do not maintain nuisance levels below
regulatory limits or dust concentration is unknown, use a NIOSH-Approved Air
Purifying Respirator. |
Eye Protection |
Wear ANSI-approved eye protection if environment is excessively dusty. |
Hand Protection |
If skin is broken or sensitive, use gloves |
Other Protective Clothing |
None |
Ventilation |
Normal and adequate ventilation |
Work/Hygienic Practices |
Standard hygienic practices |
Occupational Exposure
Limits |
Thisproductislisted/regulatedbyOSHA,Cal/OSHAandACGIHas“Particulates
NotOtherwiseClassified”or“NuisanceDust.” |
SECTION 8 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance |
Gray, odorless fiber |
Boiling/Melting Point |
Not applicable |
Bulk Density |
9 lb/ft3 compressed |
Flash Point |
Not applicable |
Vapor Pressure |
Negligible @ 20 ° C |
pH |
<8.2 (2.0% suspension @ 25° C |
Solubility in Water |
Product is not soluble |
Viscosity |
Not applicable |
SECTION 9 - STABILITY AND REACTIVITY
Stability: CelluBOR Insulation is a stable product.
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur
Conditions and Materials to Avoid: Reaction with strong reducing agents such as metal hydrides or alkali metals will generate hydrogen gas which could create an explosi ve hazard. Keep away from strong oxidizers, such as concentrated nitric acid, hydrogen peroxide and chlorine.
SECTION 10 - TOXICOLOGICAL INFORMATION
BORIC ACID |
Eye |
None listed, is expected to be an eye irritant |
Skin |
Mild irritation based on Standard Draize Test. LDLo, skin, human, 1200 mg/kg |
Ingestion |
LDLo, oral, human, 429 mg/kg. LD40, oral, rat, 2600 mg/kg |
Inhalation |
LCLo, inhalation, rat, 28 mg/m3/4H |
Subchronic |
TDLo, oral, rat, 45 gm/kg/90D-C |
Chronic |
TDLo, oral, rat, 244 gm/kg/2Y -C |
Teratology |
None reported |
Reproduction |
TDLo, oral, rat, 6600 mg/kg, specific developmental abnormalities - musculoskeletal system |
Mutagenicity Mutation in microorganisms, Escherichia Coli, 17000 ppm/24H.
BORAX PENTAHYDRATE |
Eye |
Mild eye irritant in rabbits. Fifty years of occupational exposure to borax pentahydrate indicate no adverse effects on human eye. Borax pentahydrate is a constituent of eye lotions. |
Skin |
Non-irritant. Low acute dermal toxicity; LD50 in rabbits is greater than 2,000 mg/kg of body weight. Borax pentahydrate is poorly absorbed through intact skin. |
Ingestion |
Low acute oral toxicity; LD50 in rats is 3,200 to 3,500 mg/kg of body weight |
Inhalation |
Low acute inhalation toxicity; LC50 in rats is greater than 2.0 mg/l (or g/m3). |
Subchronic |
None reported |
Chronic |
None reported |
Teratology |
None reported |
Reproduction |
None reported |
Mutagenicity |
None reported |
SECTION 11 - ECOLOGICAL INFORMATION
BORIC ACID |
Ecotoxicity |
LC50, Daphnia magna, 133 mg/l/48H. RfD, oral, human, 0.09 mg/kg/day, testicular
atrophy, spermatogenic arrest. LC50, Trout, 100 ppm |
Chemical Fate
Information |
Boron is absorbed into clay particles, with the maximum absorption in the pH range of 7-
9. The amount of boron absorbed depends on the surface area of the clay. |
BORAX PENTAHYDRATE |
Ecotoxicity |
Boron occurs naturally in sea water at an average concentration of 5 mg B/l and fresh water at 1 mg B/l or less. In dilute aqueous solutions the predominant boron species present is undissociated boric acid. |
Chemical Fate
Information |
Not listed. |
SECTION 12 - DISPOSAL CONSIDERATIONS
Dispose as a non -hazardous waste.
SECTION 13 - TRANSPORT INFORMATION
May be shipped normally as a non -hazardous material.
INTERNATIONAL REGULATIONS
Land
- Rail/road (RID/ADR) : NOT REGULATÝONS.
- Sea (IMO/IMDG) : NOT REGULATIONS.
- Air (ICAO-IATA) : NOT REGULATIONS.
OTHER REGULATIONS : NOT AVAIABLE.
NOT RESTRICTED UNDER IATA REGULATION
SECTION 14 - REGULATORY INFORMATION
Superfund: This product is not listed under the Comprehensive Environmental Response
Compensation and Liability Act (CERCLA) or its 1986 amendments, the Superfund Amendments and Reauthorization Act
(SARA), including substances listed under Section 313 of SARA, Toxic Chemicals, 42 USC 11023, 40 CFR 372.65; Section 302 of SARA Extremely Haz ardous Substances, 42 USC 11002, 40 CFR 355; or the CERCLA Hazardous Substances list, 42 USC 9604, 40 CFR 302.
RCRA: This product is not listed as a hazardous waste under any sections of the Resource Conservation and Recovery
Act or regulations (40 CFR 261 et seq.).
Safe Drinking Water Act: This product is not regulated under the SDWA, 42 USC 300g-1, 40 CFR 141 et seq. Consult state and
local regulations for possible water quality advisories regarding boron and ammonia.
California Proposition 65: This product is not listed on any Proposition 65 lists of carcinogens or reproductive toxicants.
OSHA Carcinogen: Not listed.
Clean Water Act (Federal Water Pollution Control Act): 33 USC 1251 et seq.: This product is not itself a discharge
covered by any water quality criteria of Section 304 of the CWA, 33 USC 1314. This product is not on the Section 307
List of Priority Pollutants, 33 USC 1317, 40 CFR 116. This product is not on the Section 311 List of Hazardous
Substances, 33 USC 1321, 40 CFR 116.
TSCA No.: This product does not appear on the EPA TSCA inventory list. Ammonium sulfate and boric acid appear on the EPA TSCA inventory list under the CAS Nos. 7783-20-2 and 10043-35-3 respectively.
OSHA/Cal/OSHA: This MSDS document meets the requirements of both OSHA and Cal/OSHA hazard communication standards. Refer to Section 8 for regulatory exposure limits.
IARC: The International Agency for Research on Cancer (of the World Health Organization) does not list or categorize this product as a carcinogen.
NTP Annual Report on Carcinogens: Not listed.
SECTION 15 - OTHER INFORMATION
INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED DEPENDABLE AND
IS ACCURATE AND RELIABLE TO THE BEST OF OUR KNOWLEDGE AND BELIEF, BUT IS NOT GUARANTEED TO
BE SO. NOTHING HEREIN IS TO BE CONSTRUED AS RECOMMENDING ANY PRACTICE OR ANY PRODUCT IN VIOLATION OF ANY PATENT OR IN VIOLATION OF ANY LAW OR REGULATION. THE USER IS RESPONSIBLE TO
DETERMINE THE SUITABILITY OF ANY MATERIAL FOR A SPECIFIC PURPOSE AND ADOPT NECESSARY SAFETY PRECAUTIONS. WE MAKE NO WARRANTY AS TO RESULTS TO BE OBTAINED IN USING ANY MATERIAL AND, SINCE CONDITIONS OR USE ARE NOT UNDER OUR CONTROL, WE MUST NECESSARILY DISCLAIM ALL LIABILITY WITH RESPECT TO USE OF ANY MATERIAL SUPPLIED BY US.
ABBREVIATIONS
CAS |
Chemical Abstract Services (identifies specific
chemical) |
OSHA |
Occupational Safety and Health Administration |
mg/m3 |
Grams per cubic meter |
PNOC |
Particulates Not Otherwise Classified |
LCLo |
Lethal concentration low |
PEL |
OSHA Permissible Exposure Limit |
LDLo |
Lethal dose low |
ppm |
Parts per million |
LC50 |
Lethal concentration 50% |
RfD |
Reference Dose |
LD50 |
Lethal dose 50% |
RTECS |
Registry of Toxic Effects of Chemical Substances |
LOAEL |
Lowest Observed Adverse Effect Level |
TDLo |
Toxic dose low |
Mg/l/H |
Milligrams per liter per hour |
TLV |
ACGIH Threshold Limit Value |
Mg/kg |
Milligrams per kilogram |
TWA |
8 hour Time Weighted Average exposure |
Mg/ m3 |
Milligrams per cubic meter |
|
|
BIBLIOGRAPHY
1. The Guide to Occupational Exposure Values, American Conference of Governmental Industrial Hy gienists, 1997.
2. Registry of Toxic Effects of Chemical Substances, National Institute of Occupational Safety and Health, Q-1,
1998.
3. Dangerous Properties of Industrial Materials, Sax’s, 1997 CD -Folio.
4. Hazardous Substances Data Bank, Canadian Centre for Occupational Health and Safety, Q-1, 1998.
5. Integrated Risk Information System, EPA, on-line.
6. Toxicological Profiles, Agency for Toxic Substances and Disease Registry, U.S. Public Health Service, 1997.
7. TLVs and other Occupational Exposure Values, American Conference of Governmental Industrial Hygienists,
1996.
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